Inequality in labeling chemicals

DSCN5781

As a student who has studied chemicals, it is interesting to see huge tankers carrying chemicals. If you observe these tankers closely, you will see symbols on these tankers. By understanding these symbols, one can prevent injuries, not just in chemical factories but also in offices, homes and places where chemicals are used. This is because it is not only the tankers that bear such information, other products have them too.

The picture above is of NH3 on NH17. NH3 is the chemical formula for ammonia. The photo was shot on one of India’s national highways NH17, one of the busiest and 7th longest in the country. The tanker has a lot of indicators on it. Let’s look at what these indicators mean:

  • Rear lights – indicate the speed of the vehicle
  • Reflective triangle – a warning of a vehicle ahead; shines in the dark when a vehicle behind it uses headlights
  • Number plate – identification of the tank
  • Chemical name – name of the chemical the tank is carrying
  • Two hazard symbols (aka pictograms) – skull-crossbones and a diamond placard

Tankers like these are a usual sight on these roads, considering India is the 2nd largest producer of ammonia in the world. It’s not surprising because India has a huge population and it is also the 2nd largest in terms of agricultural output. The tankers are especially striking when they give off odor. We all know that ammonia doesn’t smell nice. Cosmetic products try to avoid it but every now and then you can smell it off of someone with some fresh dye on their hair. Cosmetic products often say ‘No ammonia’ or ‘Ammonia free’ for this reason. Ammonia is also used in fertilizers, cleaning products, explosives, dyes, water purification and a lot more.

Quick facts about ammonia

  • Poisonous for short-term exposure, a 2,500 ppm (0.25%) concentration in air may be fatal within 30 minutes.
  • Fire hazard at high concentrations and high temperature
  • Water polluting as it easily dissolves in water and forms ammonium hydroxide
  • Colorless gas
  • Corrosive
DSCN5781

We can learn something about every chemical from the writing and symbols on the tanker that carries it. This tanker has the word ‘Liquid Ammonia’ on it, along with symbols of a skull-crossbones and a fire placard with the no. 2 in it.

The tanker in the picture is carrying liquefied compressed ammonia gas. A liquefied gas is a gas when packaged under pressure for transport is partially liquid at temperatures above – 50 degree C. Gay-Lussac’s law says that as the pressure goes up, the temperature also goes up, and vice-versa. Because it is pressurized, it is at a lower temperature too, so no external cooling needed.

The skull-crossbones symbol is that of a toxic/poisonous chemical and a diamond placard with a number on it needs a bit of an explanation.

The fire symbol on the diamond means that it is a flammable substance. The number on the diamond signifies which class the chemical belongs to, which in this case is Class 2. Class 2 substances are gases.

Mind you, the hazard symbol in this picture is an old convention. A pictorial list of old hazard symbols can be found here. It is now time that we speak about inequality in labeling chemicals.

Photo by Chromatograph on Unsplash

In Rio de Janeiro in the year 1992, at the UN Conference on the Environment and Development, a consistent system was developed so that if anyone from any part of the world sees these symbols, they will know what it means irrespective of the country they belong to, irrespective of the culture or language they speak. This system is called the Globally Harmonized System (GHS).

In India, there were other related rules under Environment (Protection) Act, 1986 before it considered the idea of having a GHS, such as:

  • Manufacture, Storage and Import of Hazardous Chemical Rules, 1989, 2000
  • ™Chemical Accidents (Emergency Planning, Preparedness and Response) Amendment Rules, 1996
  • ™Public Liability Insurance Act, 1991, 1992
  • Health & Safety Related Laws & Regulations:
    • ™Factories Act, 1948, 1987
    • ™Explosives Act, 1889
    • Gas Cylinder Rules, 1981
    • ™Petroleum Act, 1934, Rules, 1976
    • ™Motor Vehicle Act, 1988

According to Ministry of Environment and Forests, India, following rules were to be followed while labeling tankers carrying hazardous chemicals:

An occupier shall not handle a material which is hazardous for supply and transport unless the material is clearly marked in accordance with the following requirements, namely:

  • diamond placard (read all its specifications here)
  • on an orange rectangular panel (read all its specifications here), to be placed immediately adjacent to each placard displaying therein the United Nation number for the goods in black digits.  (UN number is a four digit serial number assigned to the substance under the United Nations system.)
  • the product name including the trade name, substance name, systematic chemical name and chemical identifiers such as Chemical Abstract Number, as applicable;
  • the name and address of the manufacturer, importer, wholesaler or other supplier of the material, and including of any deemed necessary for traceability of the material to the manufacturer or producer;
  • an emergency telephone number manned in Hindi or English twenty-four hours must be indicated on the container, iso-container or tanker; (Now you remember this one very clearly.)
  • The following information on the substance, if it considered hazardous, namely:
    • proper shipping name
    • United Nation number
    • hazard class
    • secondary hazard
    • packing group
  • the labels shall be displayed on at least two sides of the container, iso-container or tanker or transport unit

In the year 2012, India was supposed to issue rules to implement GHS but there was no news after that. Five years later, in 2017, a committee was constituted to prepare a National Action Plan for Chemicals (NAPC). A draft as seen by Chemical Watch recommends the development of an inventory and registration scheme for chemicals and outlines plans to adopt the Globally Harmonized System (GHS) of classifying and labelling chemicals. Finally!

This post was updated on May 5, 2020 for accuracy and comprehensiveness.

8 thoughts on “Inequality in labeling chemicals

  1. At RTO, most of these symbols are shown during drivers license test. But people memorize them for the sake of getting through test, without giving a thought as to why they are made to read it on the first place. Govt must find an alternative for it.

    Like

    1. Too bad I don’t remember any of the symbols shown at the RTO myself. Thanks for pointing it out. May be we can reach out to organizations like Save Life Foundation.

      Like

  2. The symbols tell us that the tanker truck transports a toxic and flammable gas (# 2).
    http://en.wikipedia.org/wiki/Dangerous_goods#Classification_and_labeling_summary_tables
    Good that the name of the chemical is written in English: Liquified Ammonia.

    In general, if I were in charge, Risk- http://en.wikipedia.org/wiki/List_of_R-phrases and Safety-Satements http://en.wikipedia.org/wiki/List_of_S-phrases should be a required component of the labeling of all chemicals, worldwide.

    I am surprised that the number plate is hand-written!

    Hopefully, the valves on these tanker trucks are inspected regularly & exchanged if found deficient. Just in case, I will stay more than 10 feet away. :-)

    And use my horn when over-taking it. :-)
    “Horn O-K Please” it must be very noisy on Indian Roads.

    Like

    1. I agree, Dirk. Safety should be of a uniform standard. Where you are, the chemicals and their effects are going to be same right?

      I think there is a rule that asks to stay a certain feet away from such tankers, I think it is 15 feet. I’m not sure where I read it though.

      Noisy? I don’t know. Someone who is new to these roads might know the difference actually. For example, if you stayed at a place for years. A place where the airport is nearby. After many years you won’t even notice the roar of the airplanes.

      Like

  3. This is a big thing here in uk. Correct labelling.. and if not labelled properly people are fined and it does the trick..

    need to be put in india too as it is very hazardous

    Like

    1. The labeling is all there in India, except it is old. I don’t understand why the delay in having a uniform labeling system.

      Like

Join the discussion

Fill in your details below or click an icon to log in:

WordPress.com Logo

You are commenting using your WordPress.com account. Log Out /  Change )

Google photo

You are commenting using your Google account. Log Out /  Change )

Twitter picture

You are commenting using your Twitter account. Log Out /  Change )

Facebook photo

You are commenting using your Facebook account. Log Out /  Change )

Connecting to %s

This site uses Akismet to reduce spam. Learn how your comment data is processed.